Relative humidity

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A hygrometer used to measure the humidity of air.

Relative humidity is a term used to describe the quantity of water vapor that exists in a gaseous mixture of air and water.

1 Definition
2 Misconceptions
3 Related concepts
4 Other important facts
5 See also
6 External links

[edit] Definition

Relative humidity is defined as the ratio of the partial pressure of water vapor in a gaseous mixture of air and water to the saturated vapor pressure of water at a given temperature. Relative humidity is expressed as a percentage and is calculated in the following manner:

$RH = {p_{(H_2O)} \over p^*_{(H_2O)}} \times 100%$

where:

$RH_{\,_\,}$ is the relative humidity of the gas mixture being considered

${p_{(H_2O)}}$ is the partial pressure of water vapor in the gas mixture;

${p^*_{(H_2O)}}$ is the saturated vapor pressure of water at the temperature of the gas mixture.

• Himmelblau, David M. (1989). Basic Principals and Calculations in Chemical Engineering. Prentice Hall. ISBN 0-13-066572.

• Perry, R.H. and Green, D.W (1997). Perry's Chemical Engineers' Handbook (7th Edition). McGraw-Hill. ISBN 0-07-049841-5.

[edit] Misconceptions

Relative humidity is the ratio of the amount of water vapor in air to the maximum amount of water vapor that could be in the air if the vapor were at its saturation conditions. Often the concept of air holding water vapor is used in the description of relative humidity. Relative humidity is wholly understood in terms of the physical properties of water alone and therefore is unrelated to this concept. [1]

This misconception is likely a result of the word saturation which is commonly used in definitions of relative humidity. Saturation used in this context refers to the thermodynamic saturation state of water vapor not the solubility of one material in another.

[edit] Related concepts

The term relative humidity is reserved for systems of water vapor in air. The term relative saturation is used to describe the analogous property for systems consisting of a condensable phase other than water or a non-condensable phase other than air. [2]

The relative humidity of a system is dependent not only on the temperature but also on the absolute pressure of the system of interest. Therefore, a change in relative humidity can be explained by a change in system temperature, a change in the absolute pressure of the system, or change in both of these system properties.

[edit] Other important facts

A gas in this context is referred to as saturated when the vapor pressure of water in the air is at the equilibrium vapor pressure for water vapor at the temperature of the gas and water vapor mixture; liquid water (and ice, at the appropriate temperature) will fail to lose mass through evaporation when exposed to saturated air. It may also correspond to the possibilility of dew or fog forming, within a space that lacks temperature differences among its portions, for instance in response to decreasing temperature. Fog consists of very minute droplets of liquid, primarily held aloft by isostatic motion.

The statement that relative humidity can never be above 100%, while a fairly good guide, is not absolutely accurate, without a more sophisticated definition of humidity than the one given here. An arguable exception is the Wilson cloud chamber which uses, in nuclear physics experiments, an extremely brief state of "supersaturation" to accomplish its function.

For a given dewpoint and its corresponding absolute humidity, the relative humidity will change inversely, albeit nonlinearly, with the temperature. This is because the partial pressure of water increases with temperature – the operative principle behind everything from hair dryers to dehumidifiers.

Due to the increasing potential for a higher water vapor partial pressure at higher air temperatures, the water content of air at sea level can get as high as 3% by mass at 30 °C (86 °F) compared to no more than about 0.5% by mass at 0 °C (32 °F). This explains the low levels (in the absence of measures to add moisture) of humidity in heated structures during winter, indicated by dry skin, itchy eyes, and persistence of static electric charges. Even with saturation (100% humidity) outdoors, heating of infiltrated outside air that comes indoors raises its moisture capacity and is reflected in a lower indoor relative humidity and increased evaporation rates from moist surfaces indoors.

Similarly, during summer in humid climates a great deal of liquid water condenses from air cooled in air conditioners. Warmer air is cooled below its dewpoint and the excess water vapor condenses. This phenomenon is the same as that which causes water droplets to form on the outside of a cup containing an ice-cold drink.

Water vapor is a lighter gas than air at the same temperature, so humid air will tend to rise by natural convection. This is a mechanism behind thunderstorms and other weather phenomena. Relative humidity is often mentioned in weather forecasts and reports, as it is an indicator of the likelihood of precipitation, dew, or fog. In hot summer weather, it also increases the apparent temperature to humans (and other animals) by hindering the evaporation of perspiration from the skin as the relative humidity rises. This effect is calculated as the heat index or humidex.

A device used to measure humidity is called a hygrometer, one used to regulate it is called a humidistat, or sometimes hygrostat. (These are analogous to a thermometer and thermostat for temperature, respectively.)